Search results
Results From The WOW.Com Content Network
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO 4. It is a white crystalline solid that is odorless and insoluble in water . It occurs in nature as the mineral barite , which is the main commercial source of barium and materials prepared from it.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitation occurs more rapidly from a strongly supersaturated solution. The formation of a precipitate can be caused by a chemical reaction. When a barium chloride solution reacts with sulphuric acid, a white precipitate of barium sulphate is formed.
Like all soluble barium compounds, barium nitrate is toxic by ingestion or inhalation. [8] Solutions of sulfate salts such as Epsom salts or sodium sulfate may be given as first aid for barium poisoning, as they precipitate the barium as the insoluble (and non-toxic) barium sulfate. Inhalation may also cause irritation to the respiratory tract.
Radium sulfate is the most insoluble sulfate known. The barium derivative is useful in the gravimetric analysis of sulfate: if one adds a solution of most barium salts, for instance barium chloride, to a solution containing sulfate ions, barium sulfate will precipitate out of solution as a whitish powder. This is a common laboratory test to ...
Solutions of barium bromide reacts with the sulfate salts to produce a solid precipitate of barium sulfate. BaBr 2 + SO 2− 4 → BaSO 4 + 2 Br −. Similar reactions occur with oxalic acid, hydrofluoric acid, and phosphoric acid, giving solid precipitates of barium oxalate, fluoride, and phosphate, respectively.
Gravimetric analysis describes a set of methods used in analytical chemistry for the quantitative determination of an analyte (the ion being analyzed) based on its mass. The principle of this type of analysis is that once an ion's mass has been determined as a unique compound, that known measurement can then be used to determine the same analyte's mass in a mixture, as long as the relative ...
Its solutions react with sulfate ion to produce a thick white solid precipitate of barium sulfate. BaCl 2 + Na 2 SO 4 → 2 NaCl + BaSO 4. This precipitation reaction is used in chlor-alkali plants to control the sulfate concentration in the feed brine for electrolysis. Oxalate effects a similar reaction: BaCl 2 + Na 2 C 2 O 4 → 2 NaCl + BaC ...