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Carbothermic reactions involve the reduction of substances, often metal oxides (O 2-), using carbon (C) as the reducing agent. The reduction is usually conducted in the electric arc furnace or reverberatory furnace, depending on the metal ore. These chemical reactions are usually conducted at temperatures of several hundred degrees Celsius ...
The Ellingham diagram plots the Gibbs free energy change (ΔG) for each oxidation reaction as a function of temperature. For comparison of different reactions, all values of ΔG refer to the reaction of the same quantity of oxygen, chosen as one mole O (1 ⁄ 2 mol O 2) by some authors [2] and one mole O 2 by others. [3] The diagram shown ...
These reactions are exothermic and the rise in temperature is usually in the order of the reactivity of the different metals. [5] If the reactant in elemental form is not the more reactive metal, then no reaction will occur. Some examples of this would be the reverse. + No Reaction
The result of the carbothermic reaction is a layer of silicon carbide (especially in its alpha and beta phases) [1] forming around the rod and emission of carbon monoxide (CO). There are four chemical reactions in the production of silicon carbide: [3] C + SiO 2 → SiO + CO; SiO 2 + CO → SiO + CO 2; C + CO 2 → 2CO; SiO + 2 C → SiC + CO
The end products are usually molten metal and slag phases tapped from the bottom, and waste gases exiting from the top of the furnace. [2] The downward flow of the ore along with the flux in contact with an upflow of hot, carbon monoxide-rich combustion gases is a countercurrent exchange and chemical reaction process. [3]
This conversion entails two parts. First is the carbothermic reaction whereby the coal, a source of carbon, reduces the sulfate to sulfide: Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. In the second stage, is the reaction to produce sodium carbonate and calcium sulfide. This mixture is called black ash. [citation needed] Na 2 S + CaCO 3 → Na 2 CO 3 + CaS
This page was last edited on 2 October 2012, at 00:24 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
Today, ferromanganese can be still efficiently produced in a blast furnace, but, even in this case, electric arc furnace are spreading. More commonly, ferroalloys are produced by carbothermic reactions, involving reduction of oxides with carbon (as coke) in the presence of iron. Some ferroalloys are produced by the addition of elements into ...