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Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
The tree model requires languages to evolve exclusively through social splitting and linguistic divergence. In the “tree” scenario, the adoption of certain innovations by a group of dialects should result immediately in their loss of contact with other related dialects: this is the only way to explain the nested organisation of subgroups imposed by the tree structure.
The Schrödinger equation for the electron in a hydrogen atom (or a hydrogen-like atom) is = where is the electron charge, is the position of the electron relative to the nucleus, = | | is the magnitude of the relative position, the potential term is due to the Coulomb interaction, wherein is the permittivity of free space and = + is the 2-body ...
In the end, the model was replaced by the modern quantum-mechanical treatment of the hydrogen atom, which was first given by Wolfgang Pauli in 1925, using Heisenberg's matrix mechanics. The current picture of the hydrogen atom is based on the atomic orbitals of wave mechanics, which Erwin Schrödinger developed in 1926.
However, several observations could not be explained by any wave model of electromagnetic radiation, leading to the idea that light-energy was packaged into quanta described by E = hν. Later experiments showed that these light-quanta also carry momentum and, thus, can be considered particles : The photon concept was born, leading to a deeper ...
In a mathematical sense, these wave functions are the basis set of functions, the basis functions, which describe the electrons of a given atom. In chemical reactions , orbital wavefunctions are modified, i.e. the electron cloud shape is changed, according to the type of atoms participating in the chemical bond .
Louis de Broglie's early results on the pilot wave theory were presented in his thesis (1924) in the context of atomic orbitals where the waves are stationary.Early attempts to develop a general formulation for the dynamics of these guiding waves in terms of a relativistic wave equation were unsuccessful until in 1926 Schrödinger developed his non-relativistic wave equation.
A molecule is here regarded as a set of nuclei, around each of which is grouped an electron configuration closely similar to that of a free atom in an external field, except that the outer parts of the electron configurations surrounding each nucleus usually belong, in part, jointly to two or more nuclei....