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Triplet oxygen, 3 O 2, refers to the S = 1 electronic ground state of molecular oxygen (dioxygen). Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradical : [ 2 ] it is more stable as a triplet than a singlet .
Oxygen is the third most abundant chemical element in the universe, after hydrogen and helium. [68] About 0.9% of the Sun's mass is oxygen. [19] Oxygen constitutes 49.2% of the Earth's crust by mass [69] as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust.
The unpaired electrons participate in three-electron bonding, shown here using dashed lines. The common allotrope of elemental oxygen on Earth, O 2, is generally known as oxygen, but may be called dioxygen, diatomic oxygen, molecular oxygen, dioxidene or oxygen gas to distinguish it from the element itself and from the triatomic allotrope ozone ...
Dark oxygen production refers to the generation of molecular oxygen (O 2) through processes that do not involve light-dependent oxygenic photosynthesis.The name therefore uses a different sense of 'dark' than that used in the phrase "biological dark matter" (for example) which indicates obscurity to scientific assessment rather than the photometric meaning.
The molecule, therefore, has two unpaired electrons and is in a triplet state. In contrast, the first and second excited states of dioxygen are both states of singlet oxygen. Each has two electrons of opposite spin in the π* level so that S = 0 and the multiplicity is 2S + 1 = 1 in consequence.
Within a molecule, electrons move under the influence of several nuclei, and occupy molecular orbitals; much as they can occupy atomic orbitals in isolated atoms. [128] A fundamental factor in these molecular structures is the existence of electron pairs. These are electrons with opposed spins, allowing them to occupy the same molecular orbital ...
In theoretical chemistry, molecular electronic transitions take place when electrons in a molecule are excited from one energy level to a higher energy level. The energy change associated with this transition provides information on the structure of the molecule and determines many of its properties, such as colour.
Relatively more stable entities with unpaired electrons do exist, e.g. the nitric oxide molecule has one. According to Hund's rule, the spins of unpaired electrons are aligned parallel and this gives these molecules paramagnetic properties. The most stable examples of unpaired electrons are found on the atoms and ions of lanthanides and ...