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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
Fitting of a noisy curve by an asymmetrical peak model, with an iterative process (Gauss–Newton algorithm with variable damping factor α).Curve fitting [1] [2] is the process of constructing a curve, or mathematical function, that has the best fit to a series of data points, [3] possibly subject to constraints.
When these assumptions are satisfied, the following covariance matrix K applies for the 1D profile parameters , , and under i.i.d. Gaussian noise and under Poisson noise: [9] = , = , where is the width of the pixels used to sample the function, is the quantum efficiency of the detector, and indicates the standard deviation of the measurement noise.
About 68% of values drawn from a normal distribution are within one standard deviation σ from the mean; about 95% of the values lie within two standard deviations; and about 99.7% are within three standard deviations. [8] This fact is known as the 68–95–99.7 (empirical) rule, or the 3-sigma rule.
The standard deviation is the square root of the variance. When individual determinations of an age are not of equal significance, it is better to use a weighted mean to obtain an "average" age, as follows: x ¯ ∗ = ∑ i = 1 N w i x i ∑ i = 1 N w i . {\displaystyle {\overline {x}}^{*}={\frac {\sum _{i=1}^{N}w_{i}x_{i}}{\sum _{i=1}^{N}w_{i}}}.}
In statistics, the Q-function is the tail distribution function of the standard normal distribution. [1] [2] In other words, () is the probability that a normal (Gaussian) random variable will obtain a value larger than standard deviations.
In other words, it is the width of a spectrum curve measured between those points on the y-axis which are half the maximum amplitude. Half width at half maximum (HWHM) is half of the FWHM if the function is symmetric. The term full duration at half maximum (FDHM) is preferred when the independent variable is time.
In simple cases, this function can be represented as a two-dimensional graph of an independent scalar input versus the dependent scalar output (known as a transfer curve or characteristic curve). Transfer functions for components are used to design and analyze systems assembled from components, particularly using the block diagram technique, in ...