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Tafel plot for an anodic process . The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.
The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium).
the slope field is an array of slope marks in the phase space (in any number of dimensions depending on the number of relevant variables; for example, two in the case of a first-order linear ODE, as seen to the right). Each slope mark is centered at a point (,,, …,) and is parallel to the vector
It has also been called Sen's slope estimator, [1] [2] slope selection, [3] [4] the single median method, [5] the Kendall robust line-fit method, [6] and the Kendall–Theil robust line. [7] It is named after Henri Theil and Pranab K. Sen , who published papers on this method in 1950 and 1968 respectively, [ 8 ] and after Maurice Kendall ...
This illustrates clearly demonstrates the effectiveness of the MUSCL approach to solving the Euler equations. The simulation was carried out on a mesh of 200 cells using Matlab code (Wesseling, 2001), adapted to use the KT algorithm and Ospre limiter. Time integration was performed by a 4th order SHK (equivalent performance to RK-4) integrator.
The admissible limiter region for second-order TVD schemes is shown in the Sweby Diagram opposite, [9] and plots showing limiter functions overlaid onto the TVD region are shown below. In this image, plots for the Osher and Sweby limiters have been generated using β = 1.5 {\displaystyle \beta =1.5} .
The software developed by Deb can be downloaded, [7] which implements the NSGA-II procedure with GAs, or the program posted on Internet, [8] which implements the NSGA-II procedure with ES. Just a general form of the equation, a plot of the objective function, boundaries of the object variables and the coordinates of global minima are given herein.
For example, if the feed is a saturated liquid, q = 1 and the slope of the q-line is infinite (drawn as a vertical line). As another example, if the feed is saturated vapor, q = 0 and the slope of the q-line is 0 (a horizontal line). [2] The typical McCabe–Thiele diagram in Figure 1 uses a q-line representing a partially vaporized feed.