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The lanthanite crystal structure consists of layers of 10-fold coordinated REE-oxygen (O) polyhedra and carbonate (CO 3 2−) groups connected by hydrogen bonds to interlayer water molecules, forming a highly hydrated structure.
Lanthanum is the first element and prototype of the lanthanide series. In the periodic table, it appears to the right of the alkaline earth metal barium and to the left of the lanthanide cerium. Lanthanum is generally considered the first of the f-block elements by authors writing on the subject.
The electronic configuration of most neutral gas-phase lanthanide atoms is [Xe]6s 2 4f n, where n is 56 less than the atomic number Z. Exceptions are La, Ce, Gd, and Lu, which have 4f n −1 5d 1 (though even then 4f n is a low-lying excited state for La, Ce, and Gd; for Lu, the 4f shell is already full, and the fifteenth electron has no choice ...
Lanthanide metals react exothermically with hydrogen to form LnH 2, dihydrides. [1] With the exception of Eu and Yb, which resemble the Ba and Ca hydrides (non-conducting, transparent salt-like compounds),they form black pyrophoric, conducting compounds [6] where the metal sub-lattice is face centred cubic and the H atoms occupy tetrahedral sites. [1]
The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), [1] are a set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals.
Cerium is the second element in the lanthanide series, and while it often shows the oxidation state of +3 characteristic of the series, it also has a stable +4 state that does not oxidize water. It is considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or ...
La 2 O 3 powder. Lanthanum oxide is a white solid that is insoluble in water, but dissolves in acidic solutions. La 2 O 3 absorbs moisture from air, converting to lanthanum hydroxide. [2]
The lanthanide ions in these complexes can readily react with oxygen and water, leading to oxidation or hydrolysis, which damages the material’s structure and reduces its efficiency. This makes handling and storage difficult, requiring protective environments like sealed containers or inert gas atmospheres.