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  2. Xenon difluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_difluoride

    In the presence of liquid HF, dark green crystals can be precipitated from the green solution at −30 °C: Xe + 2 (apf) + 4 SbF − 6 (apf) → Xe + 2 Sb 4 F − 21 (s) + 3 F − (apf) X-ray crystallography indicates that the Xe–Xe bond length in this compound is 309 pm, indicating a very weak bond. [18] The Xe + 2 ion is isoelectronic with ...

  3. Xenon compounds - Wikipedia

    en.wikipedia.org/wiki/Xenon_compounds

    It explodes above −35.9 °C into xenon and oxygen gas, but is otherwise stable. A number of xenon oxyfluorides are known, including XeOF 2, XeOF 4, XeO 2 F 2, and XeO 3 F 2. XeOF 2 is formed by reacting OF 2 with xenon gas at low temperatures. It may also be obtained by partial hydrolysis of XeF 4. It disproportionates at −20 °C into XeF 2 ...

  4. Xenon oxydifluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_oxydifluoride

    Xenon oxydifluoride is an inorganic compound with the molecular formula XeOF 2.The first definitive isolation of the compound was published on 3 March 2007, producing it by the previously-examined route of partial hydrolysis of xenon tetrafluoride.

  5. Three-center four-electron bond - Wikipedia

    en.wikipedia.org/wiki/Three-center_four-electron...

    The I − lone pair acts as a 2-electron donor, while the I 2 σ* antibonding orbital acts as a 2-electron acceptor. [12] Combining the donor and acceptor in in-phase and out-of-phase combinations results in the diagram depicted at right (Figure 2). Combining the donor lone pair with the acceptor σ* antibonding orbital results in an overall ...

  6. Xenon tetrafluoride - Wikipedia

    en.wikipedia.org/wiki/Xenon_tetrafluoride

    26 languages. العربية ... 117 °C (243 °F; 390 K) sublimes [1] ... the xenon center has two lone pairs of electrons. These lone pairs are mutually trans.

  7. Lone pair - Wikipedia

    en.wikipedia.org/wiki/Lone_pair

    Thus, the number of electrons in lone pairs plus the number of electrons in bonds equals the number of valence electrons around an atom. Lone pair is a concept used in valence shell electron pair repulsion theory (VSEPR theory) which explains the shapes of molecules. They are also referred to in the chemistry of Lewis acids and bases. However ...

  8. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    The difference between lone pairs and bonding pairs may also be used to rationalize deviations from idealized geometries. For example, the H 2 O molecule has four electron pairs in its valence shell: two lone pairs and two bond pairs. The four electron pairs are spread so as to point roughly towards the apices of a tetrahedron.

  9. Trigonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_pyramidal...

    However, the three hydrogen atoms are repelled by the electron lone pair in a way that the geometry is distorted to a trigonal pyramid (regular 3-sided pyramid) with bond angles of 107°. In contrast, boron trifluoride is flat, adopting a trigonal planar geometry because the boron does not have a lone pair of electrons.