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The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
K Values Diagram (with UNIQUAC Best-Fit Curve), Mixture of Chloroform/Methanol. The tendency of a given chemical species to partition itself preferentially between liquid and vapor phases is the Henry's law constant. There can be VLE data for mixtures of four or more components, but such a boiling-point diagram is hard to show in either tabular ...
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas comes into a supercritical phase ...
Envelope (mathematics) Construction of the envelope of a family of curves. In geometry, an envelope of a planar family of curves is a curve that is tangent to each member of the family at some point, and these points of tangency together form the whole envelope. Classically, a point on the envelope can be thought of as the intersection of two ...
Flammability diagrams show the control of flammability in mixtures of fuel, oxygen and an inert gas, typically nitrogen. Mixtures of the three gasses are usually depicted in a triangular diagram, known as a ternary plot. Such diagrams are available in the speciality literature. [1][2][3] The same information can be depicted in a normal ...
Lower envelope. In mathematics, the lower envelope or pointwise minimum of a finite set of functions is the pointwise minimum of the functions, the function whose value at every point is the minimum of the values of the functions in the given set. The concept of a lower envelope can also be extended to partial functions by taking the minimum ...
Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing. The result is an equation for the Gibbs free energy change for mixing a polymer ...
Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.