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For example, the conversion factor between a mass fraction of 1 ppb and a mole fraction of 1 ppb is about 4.7 for the greenhouse gas CFC-11 in air (Molar mass of CFC-11 / Mean molar mass of air = 137.368 / 28.97 = 4.74). For volume fraction, the suffix "V" or "v" is sometimes appended to the parts-per notation (e.g. ppmV, ppbv, pptv).
The conversion equations depend on the temperature at which the conversion is wanted (usually about 20 to 25 degrees Celsius). At an ambient air pressure of 1 atmosphere (101.325 kPa), the general equation is: = / ()
In environmental chemistry we make a distinction between parts per million {or billion, etc.} by *volume* vs. ppm by *weight*. For a dilute solution, such as NaCl in water, concentration is often expressed as weight of solute divided by mass of solution (typically assuming 1 g/mL for dilute water-based solutions) -- i.e., ppm by weight.
[19] [20] Examples of quotients of dimension one include calculating slopes or some unit conversion factors. Another set of examples is mass fractions or mole fractions, often written using parts-per notation such as ppm (= 10 −6), ppb (= 10 −9), and ppt (= 10 −12), or perhaps confusingly as ratios of two identical units (kg/kg or mol/mol).
In chemistry and physics, the dimensionless mixing ratio is the abundance of one component of a mixture relative to that of all other components. The term can refer either to mole ratio (see concentration ) or mass ratio (see stoichiometry ).
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
The equation can only be applied when the purged volume of vapor or gas is replaced with "clean" air or gas. For example, the equation can be used to calculate the time required at a certain ventilation rate to reduce a high carbon monoxide concentration in a room.
Observed concentrations have been in the range of 0.1–4.8 parts per billion in rural air, 4–10.5 ppb in urban air, and 7–260 ppb in industrial air samples. [ 9 ] In the United States and some European countries a threshold limit value of 500 parts per million ( ppm ) was established for occupational (8-hour time-weighted average ) exposure.