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2 CO 3 + OH −. Sodium bicarbonate can sometimes be used as a mild neutralization agent and a safer alternative to strong bases like sodium hydroxide. [79] Reaction of sodium bicarbonate and an acid produces a salt and carbonic acid, which readily decomposes to carbon dioxide and water: [79] NaHCO 3 + HCl → NaCl + H 2 O+CO 2 H 2 CO 3 → H 2 ...
CH 3 COOH + NaHCO 3 → CH 3 COONa + H 2 CO 3 H 2 CO 3 → CO 2 + H 2 O. Industrially, sodium acetate trihydrate is prepared by reacting acetic acid with sodium hydroxide using water as the solvent. CH 3 COOH + NaOH → CH 3 COONa + H 2 O. To manufacture anhydrous sodium acetate industrially, the Niacet Process is used.
The only hydrates with stable melting points are NaOH·H 2 O (65.10 °C) and NaOH·3.5H 2 O (15.38 °C). The other hydrates, except the metastable ones NaOH·3H 2 O and NaOH·4H 2 O (β) can be crystallized from solutions of the proper composition, as listed above. However, solutions of NaOH can be easily supercooled by many degrees, which ...