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Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t 2g orbitals.
A ball-and-stick model of VO(O 2 C 5 H 7) 2. Complexes of vanadium(II) and (III) are reducing, while those of V(IV) and V(V) are oxidants. The vanadium ion is rather large and some complexes achieve coordination numbers greater than 6, as is the case in [V(CN) 7] 4−. Oxovanadium(V) also forms 7 coordinate coordination complexes with ...
A ball-and-stick model of VO(O 2 C 5 H 7) 2. Complexes of vanadium(II) and (III) are relatively exchange inert and reducing. Those of V(IV) and V(V) are oxidants. Vanadium ion is rather large and some complexes achieve coordination numbers greater than 6, as is the case in [V(CN) 7] 4−. Oxovanadium(V) also forms 7 coordinate coordination ...
Vanadium oxide mainly refers to: Vanadium(II) oxide (vanadium monoxide), VO; Vanadium(III) oxide (vanadium sesquioxide or trioxide), V 2 O 3; Vanadium(IV) oxide (vanadium dioxide), VO 2; Vanadium(V) oxide (vanadium pentoxide), V 2 O 5; Various other distinct phases include: Phases with the general formula V n O 2n+1 exist between V 2 O 5 and VO 2.
The complex is generally prepared from vanadium(IV), e.g. vanadyl sulfate: [1] VOSO 4 + 2 Hacac → VO(acac) 2 + H 2 SO 4. It can also be prepared by a redox reaction starting with vanadium pentoxide. In this reaction, some acetylacetone is oxidized to 2,3,4-Pentanetrione. [1]
The intense blue color of Prussian blue is a consequence of an intervalence charge transfer band. In chemistry, intervalence charge transfer, often abbreviated IVCT or even IT, is a type of charge-transfer band that is associated with mixed valence compounds. It is most common for systems with two metal sites differing only in oxidation state.
The complexes [V(CN) 6] 3− and [V 2 Cl 9] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively. A simple vanadate ion is the tetrahedral orthovanadate anion, VO 3− 4 (which is also called vanadate(V)), which is present in e.g. sodium orthovanadate and in solutions of V 2 O 5 in strong base ( pH > 13 [ 1
Vanadium(II) chloride is the inorganic compound with the formula VCl 2, and is the most reduced vanadium chloride. Vanadium(II) chloride is an apple-green solid that dissolves in water to give purple solutions.