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The caesium chloride structure adopts a primitive cubic lattice with a two-atom basis, where both atoms have eightfold coordination. The chloride atoms lie upon the lattice points at the corners of the cube, while the caesium atoms lie in the holes in the center of the cubes; an alternative and exactly equivalent 'setting' has the caesium ions at the corners and the chloride ion in the center.
A network model of a primitive cubic system The primitive and cubic close-packed (also known as face-centered cubic) unit cells. In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
A primitive cell is a unit cell that contains exactly one lattice point. For unit cells generally, lattice points that are shared by n cells are counted as 1 / n of the lattice points contained in each of those cells; so for example a primitive unit cell in three dimensions which has lattice points only at its eight vertices is considered to contain 1 / 8 of each of them. [3]
The unit cell is defined as the smallest repeating unit having the full symmetry of the crystal structure. [2] The geometry of the unit cell is defined as a parallelepiped, providing six lattice parameters taken as the lengths of the cell edges (a, b, c) and the angles between them (α, β, γ). The positions of particles inside the unit cell ...
Unit cell definition using parallelepiped with lengths a, b, c and angles between the sides given by α, β, γ [1]. A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal.
Cesium chloride is a simple cubic crystal lattice with a basis of Cs at (0,0,0) and Cl at (1/2, 1/2, 1/2) (or the other way around, it makes no difference). Equation ( 8 ) becomes
The continuous reduction of M with decreasing coordination number Z for the three cubic AB compounds (when accounting for the doubled charges in ZnS) explains the observed propensity of alkali halides to crystallize in the structure with highest Z compatible with their ionic radii.
For example, the length of each edge of the unit cell of sodium chloride is found to be 564.02 pm. Each edge of the unit cell of sodium chloride may be considered to have the atoms arranged as Na + ∙∙∙Cl − ∙∙∙Na +, so the edge is twice the Na-Cl separation.