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, and Sc 3+ and the anions Cl −, S 2−, and P 3− are all isoelectronic with the Ar atom. CO, CN −, N 2, and NO + are isoelectronic because each has two atoms triple bonded together, and due to the charge have analogous electronic configurations (N − is identical in electronic configuration to O so CO is identical electronically to CN −).
These groups are characterized by i) an n-fold proper rotation axis C n; ii) n 2-fold proper rotation axes C 2 normal to C n; iii) a mirror plane σ h normal to C n and containing the C 2 s. The D 1h group is the same as the C 2v group in the pyramidal groups section. The D 8h table reflects the 2007 discovery of errors in older references. [4]
The f-block groups are ignored in this numbering. [22] Groups can also be named by their first element, e.g. the "scandium group" for group 3. [22] Previously, groups were known by Roman numerals. In the United States, the Roman numerals were followed by either an "A" if the group was in the s-or p-block, or a "B" if the group was in the d-block.
Zintl phases are intermetallic compounds that have a pronounced ionic bonding character. They are made up of a polyanionic substructure and group 1 or 2 counter ions, and their structure can be understood by a formal electron transfer from the electropositive element to the more electronegative element in their composition.
The isolobal analogy can also be used with isoelectronic fragments having the same coordination number, which allows charged species to be considered. For example, Re(CO) 5 is isolobal with CH 3 and therefore, [Ru(CO) 5] + and [Mo(CO) 5] − are also isolobal with CH 3. Any 17-electron metal complex would be isolobal in this example.
Functional groups can also be charged, e.g. in carboxylate salts (−COO −), which turns the molecule into a polyatomic ion or a complex ion. Functional groups binding to a central atom in a coordination complex are called ligands. Complexation and solvation are also caused by specific interactions of functional groups.
weak to strong (usually 3 or 4) 1500 1580 1600 C≡C terminal alkynes 2100–2140 weak disubst. alkynes 2190–2260 very weak (often indistinguishable) C=O aldehyde/ketone saturated aliph./cyclic 6-membered 1720 α,β-unsaturated 1685 aromatic ketones 1685 cyclic 5-membered 1750 cyclic 4-membered 1775 aldehydes 1725
[3] [4] Nitroxyl can be formed as a short-lived intermediate in the solution phase. The conjugate base, NO −, nitroxide anion, is the reduced form of nitric oxide (NO) and is isoelectronic with dioxygen. The bond dissociation energy of H−NO is 49.5 kcal/mol (207 kJ/mol), which is unusually weak for a bond to the hydrogen atom.