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With strong bases, the positions 4 and 6 (the two CH 2-groups of the carbonyl group and the C-C double bond adjacent) are deprotonated. Cyclohexenone is an in-vitro catalyst for a relatively mild decarboxylation of alpha amino acids .
[4] [5] In 1966, Howard E. Worne of Natick Chemical Industries patented compounds with formulas C 10 O 8 and C 14 O 10 , which can be described as the fusion of two or three molecules of C 6 O 6 , claimed to be produced by the action of ultraviolet radiation on a hot water solution of the parent compound.
Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts: [11]. C 6 H 12 + O 2 → (CH 2) 5 CO + H 2 O. This process forms cyclohexanol as a by-product, and this mixture, called "KA Oil" for ketone-alcohol oil, is the main feedstock for the production of adipic acid.
The reaction conducted in two steps beginning with the conversion of DMT to the diester dimethyl 1,4-cyclohexanedicarboxylate (DMCD): C 6 H 4 (CO 2 CH 3) 2 + 3 H 2 → C 6 H 10 (CO 2 CH 3) 2. In the second step DMCD is further hydrogenated to CHDM: C 6 H 10 (CO 2 CH 3) 2 + 4 H 2 → C 6 H 10 (CH 2 OH) 2 + 2 CH 3 OH. A copper chromite catalyst ...
The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. [1] [2] In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.
1,4-Butanediol: GHB and Gamma-Butyrolactone: Cyclohexanone: phencyclidine Diethylamine and its salts lysergic acid diethylamide ethyl 3-oxo-4-phenylbutanoate phenylacetone: ethyl-3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate (MDP2P ethyl glycidate) MDMA: Formamide: amphetamine, methamphetamine Formic acid: amphetamine, methamphetamine
Hagemann's ester, ethyl 2-methyl-4-oxo-2-cyclohexenecarboxylate, is an organic compound that was first prepared and described in 1893 by German chemist Carl Hagemann. The compound is used in organic chemistry as a reagent in the synthesis of many natural products including sterols , trisporic acids , and terpenoids .
It can be produced by a Wittig reaction or a reaction with a Tebbe's reagent from cyclohexanone. [ 1 ] [ 2 ] [ 3 ] It can also be synthesized as a side product of the dehydration of 2-methylcyclohexanol into 1-methylcyclohexene.
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