Search results
Results From The WOW.Com Content Network
Cyanide is quantified by potentiometric titration, a method widely used in gold mining. It can also be determined by titration with silver ion. Some analyses begin with an air-purge of an acidified boiling solution, sweeping the vapors into a basic absorber solution. The cyanide salt absorbed in the basic solution is then analyzed. [47]
Calcium cyanide is the inorganic compound with the formula Ca(CN) 2. It is the calcium salt derived from hydrocyanic acid. It is a white solid, although the pure material is rarely encountered. It slowly hydrolyses in solution or moist air to release hydrogen cyanide and is very toxic. [3]
The compounds have the formula RZn 2 R and ... The reason for the hydrolysis is the high electrical charge density on the zinc ion, ... The cyanide group shows head ...
Any salt containing the ion, such as ammonium cyanate, is called a cyanate. The cyanate ion is an isomer of the much-less-stable fulminate anion, CNO − or [C − ≡N + −O −]. [1] The cyanate ion is an ambidentate ligand, forming complexes with a metal ion in which either the nitrogen or oxygen atom may be the electron-pair donor.
A hydrogen cyanide concentration of 100–200 ppm in breathing air will kill a human within 10 to 60 minutes. [68] A hydrogen cyanide concentration of 2000 ppm (about 2380 mg/m 3) will kill a human in about one minute. [68] The toxic effect is caused by the action of the cyanide ion, which halts cellular respiration.
Zinc cyanide is the inorganic compound with the formula Zn 2. It is a white solid that is used mainly for electroplating zinc but also has more specialized applications for the synthesis of organic compounds .
Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions. The resulting cyanometallate anions are often used as building blocks for more complex structures called coordination polymers , the best known example of which is Prussian blue , a common dyestuff.
Sodium cyanide is a compound with the formula Na C N and the structure Na + − C≡N. It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt .