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Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
The conductivity of a water/aqueous solution is highly dependent on its concentration of dissolved salts, and other chemical species that ionize in the solution. Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher ...
The siemens (symbol: S) is the unit of electric conductance, electric susceptance, and electric admittance in the International System of Units (SI). Conductance, susceptance, and admittance are the reciprocals of resistance, reactance, and impedance respectively; hence one siemens is equal to the reciprocal of one ohm (Ω −1) and is also referred to as the mho.
κ is the measured conductivity (formerly known as specific conductance), [3] c is the molar concentration of the electrolyte. The SI unit of molar conductivity is siemens metres squared per mole (S m 2 mol −1). [2] However, values are often quoted in S cm 2 mol −1. [4]
In operating batteries and fuel cells, charge transfer coefficient is the parameter that signifies the fraction of overpotential that affects the current density.This parameter has had a mysterious significance in electrochemical kinetics for over three quarters of the previous century [citation needed].
Typically smaller than 0.01 cm 2 /(V⋅s); depends on electric field; increases with increasing temperature Starting with Ohm's law and using the definition of conductivity , it is possible to derive the following common expression for current as a function of carrier mobility μ and applied electric field E :
CF (conductivity factor) is basically EC multiplied by 10, and is used in some places because it eliminates the need for a decimal point, so an EC of 0.1 is equal to a CF of 1. [ 1 ] Electrical conductivity can be expressed using a number of different units but the international standard is EC, and the unit of measurement is usually ...
where TDS is expressed in mg/L and EC is the electrical conductivity in microsiemens per centimeter at 25 °C. The conversion factor k e varies between 0.55 and 0.8. [5] Some TDS meters use an electrical conductivity measurement to the ppm using the above formula. Regarding units, 1 ppm indicates 1 mg of dissolved solids per 1,000 g of water.