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For example, the isopropyl group (IUPAC: prop-2-yl) −CH(CH 3) 2 corresponds to the isopropylidene group =C(CH 3) 2 (IUPAC: prop-2-ylidene). The group is not typically used in common names of branched alkenes - e.g. 3-methylenepentane, the simplest compound that systematically includes an alkylidene group, [Note 1] is commonly known as 2-ethyl ...
The simplest alkene, ethylene (C 2 H 4) (or "ethene" in the IUPAC nomenclature) is the organic compound produced on the largest scale industrially. [ 5 ] Aromatic compounds are often drawn as cyclic alkenes, however their structure and properties are sufficiently distinct that they are not classified as alkenes or olefins. [ 3 ]
For example: Markovnikov's rule predicts that the hydrogen atom is added to the carbon of the alkene functional group which has the greater number of hydrogen atoms (fewer alkyl substituents). Zaitsev's rule predicts that the major reaction product is the alkene with the more highly substituted (more stable) double bond.
There are several functional groups that contain an alkene such as vinyl group, allyl group, or acrylic group. Hydrocarbons may form charged structures: positively charged carbocations or negative carbanions. Carbocations are often named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion.
For example, (CH 3) 2 CHCH 2 CH 3 (isopentane) is named 2-methylbutane, not 3-methylbutane. If there are multiple side-branches of the same size alkyl group, their positions are separated by commas and the group prefixed with multiplier prefixes depending on the number of branches. For example, C(CH 3) 4 (neopentane) is named 2,2 ...
Vinyl derivatives are alkenes. If activated by an adjacent group, the increased polarization of the bond gives rise to characteristic reactivity, which is termed vinylogous : In allyl compounds, where the next carbon is saturated but substituted once, allylic rearrangement and related reactions are observed.
Adding the hydrogen ion to one carbon atom in the alkene creates a positive charge on the other carbon, forming a carbocation intermediate. The more substituted the carbocation, the more stable it is, due to induction and hyperconjugation. The major product of the addition reaction will be the one formed from the more stable intermediate.
In organic chemistry, syn-and anti-addition are different ways in which substituent molecules can be added to an alkene (R 2 C=CR 2) or alkyne (RC≡CR).The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.