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Crystal structure of CH 3 NH 3 PbX 3 perovskites (X=I, Br and/or Cl). The methylammonium cation (CH 3 NH 3 +) is surrounded by PbX 6 octahedra. [13]The name "perovskite solar cell" is derived from the ABX 3 crystal structure of the absorber materials, referred to as perovskite structure, where A and B are cations and X is an anion.
The main obstacle to viable tin perovskite solar cells is the instability of tin's oxidation state Sn 2+, which is easily oxidized to the stabler Sn 4+. [10] In solar cell research, this process is called self-doping, [11] because the Sn 4+ acts as a p-dopant and reduces solar cell efficiency.
In January 2024, they set a new record of 25% efficiency from industrial sized solar modules. In June 2024, they set another new world record for residential solar panels achieving a 26.9% efficiency from perovskite-on-silicon tandem solar cells. This will allow consumers benefit from upwards of 20% more power from the same footprint. [13]
Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
Solar cell efficiency of perovskite solar cells have increased from 3.8% in 2009 [7] to 25.2% in 2020 in single-junction architectures, [8] and, in silicon-based tandem cells, to 29.1%, [8] exceeding the maximum efficiency achieved in single-junction silicon solar cells. [additional citation(s) needed]
A paper titled "Ageing effects of perovskite solar cells under different environmental factors and electrical load conditions" published in 2018 in the journal [2] corresponded to a paper previously published in the journal Nature Energy as "Systematic investigation of the impact of operation conditions on the degradation behaviour of perovskite solar cells". [3]
Solar cell efficiency of perovskite solar cells have increased from 3.8% in 2009 [47] to 25.2% in 2020 in single-junction architectures, [48] and, in silicon-based tandem cells, to 29.1%, [48] exceeding the maximum efficiency achieved in single-junction silicon solar cells. [additional citation(s) needed]
However, the solar cells are prone to degradation due to volatility of the organic [CH 3 NH 3] + I − salt. The all-inorganic perovskite cesium lead iodide perovskite (CsPbI 3) circumvents this problem, but is itself phase-unstable, the low temperature solution methods of which have only been recently developed. [47]