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Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, an important nickel carbonate is basic nickel carbonate with the formula Ni 4 CO 3 (OH) 6 (H 2 O) 4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO 3 and its hexahydrate.
Nickel tetrafluoroborate, Ni(BF 4) 2 · 6 H 2 O is very soluble in water, alcohol and acetonitrile. It is prepared by dissolving nickel carbonate in tetrafluoroboric acid. [21] [22] Nickel tetrafluoroberyllate NiBeF 4 •xH 2 O, can be hydrated with six or seven water molecules. [23]
Nickel carbonate NiCO 3 · 6 H 2 O, hellyerite, [13] crystallising with six water molecules, precipitates when an alkali bicarbonate is added to a Ni aqueous solution. [1] Basic nickel carbonate, zaratite, with the formula Ni 4 CO 3 (OH) 6 (H 2 O) 4, is produced when alkali carbonates are added to a nickel solution.
Nickel maleate can be made from maleic acid and nickel carbonate in boiling water. A dihydrate crystallises from the water solution. [11] Nickel fumarate prepared from fumaric acid and nickel carbonate is pale green as a tetrahydrate, and mustard coloured as an anhydride. It decomposes when heated to 300° to 340° in vacuum.
Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Actinium(III) hydroxide ... Nickel(II) carbonate: NiCO 3: 9.643× ...
Double fluorides include the above-mentioned fluoroanion salts, and those fluoronickelates such as NiF 4 and NiF 6.Other odd ones include an apple green coloured KNiF 3 ·H 2 O and NaNiF 3 ·H 2 O, aluminium nickel pentafluoride AlNiF 5 ·7H 2 O, ceric nickelous decafluoride Ce 2 NiF 10 ·7H 2 O, niobium nickel fluoride Ni 3 H 4 Nb 2 F 20 ·19H 2 O, vanadium nickel pentafluoride VNiF 5 ·7H 2 ...
Nickel(II) oxide is the chemical compound with the formula NiO. It is the principal oxide of nickel. [4] It is classified as a basic metal oxide. Several million kilograms are produced annually of varying quality, mainly as an intermediate in the production of nickel alloys. [5] The mineralogical form of NiO, bunsenite, is very rare.
Zaratite is a bright emerald green nickel carbonate mineral with formula Ni 3 CO 3 (OH) 4 ·4H 2 O. Zaratite crystallizes in the isometric crystal system as massive to mammillary encrustations and vein fillings. It has a specific gravity of 2.6 and a Mohs hardness of 3 to 3.5.