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The formal definition of calibration by the International Bureau of Weights and Measures (BIPM) is the following: "Operation that, under specified conditions, in a first step, establishes a relation between the quantity values with measurement uncertainties provided by measurement standards and corresponding indications with associated measurement uncertainties (of the calibrated instrument or ...
In addition, calibration is used in statistics with the usual general meaning of calibration. For example, model calibration can be also used to refer to Bayesian inference about the value of a model's parameters, given some data set, or more generally to any type of fitting of a statistical model.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The calibration curve can then be used to calculate the analyte concentration in an unknown sample. [1] Selecting an appropriate internal standard accounts for random and systematic sources of uncertainty that arise during sample preparation or instrument fluctuation.
Calibration training improves subjective probabilities because most people are either "overconfident" or "under-confident" (usually the former). [3] By practicing with a series of trivia questions, it is possible for subjects to fine-tune their ability to assess probabilities. For example, a subject may be asked:
An example of a secondary standard is sodium hydroxide, a hydroscopic compound that is highly reactive with its surroundings. The concentration of a standard solution made with sodium hydroxide may fluctuate overtime due to the instability of the compound, requiring for calibration using a primary standard before use. [3] [5]