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In the history of science, the mechanical equivalent of heat states that motion and heat are mutually interchangeable and that in every case, a given amount of work would generate the same amount of heat, provided the work done is totally converted to heat energy. The mechanical equivalent of heat was a concept that had an important part in the ...
The calorie is defined as the amount of thermal energy necessary to raise the temperature of one gram of water by 1 Celsius degree, from a temperature of 14.5 °C, at a pressure of 1 atm. For thermochemistry a calorie of 4.184 J is used, but other calories have also been defined, such as the International Steam Table calorie of 4.1868 J.
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
Specific heat capacity is also related to other intensive measures of heat capacity with other denominators. If the amount of substance is measured as a number of moles, one gets the molar heat capacity instead, whose SI unit is joule per kelvin per mole, J⋅mol −1 ⋅K −1.
The therm (symbol, thm) is a non-SI unit of heat energy equal to 100,000 British thermal units (BTU), [1] and approximately 105 megajoules, 29.3 kilowatt-hours, 25,200 kilocalories and 25.2 thermies. One therm is the energy content of approximately 100 cubic feet (2.83 cubic metres) of natural gas at standard temperature and pressure .
It follows from Carathéodory's principle that quantity of energy quasi-statically transferred as heat is a holonomic process function, in other words, =. [ 50 ] Though it is almost customary in textbooks to say that Carathéodory's principle expresses the second law and to treat it as equivalent to the Clausius or to the Kelvin-Planck ...
The heat capacity of an object, denoted by , is the limit =, where is the amount of heat that must be added to the object (of mass M) in order to raise its temperature by . The value of this parameter usually varies considerably depending on the starting temperature T {\displaystyle T} of the object and the pressure p {\displaystyle p} applied ...
The calorie is a unit of energy that originated from the caloric theory of heat. [ 1 ] [ 2 ] The large calorie , food calorie , dietary calorie , kilocalorie , or kilogram calorie is defined as the amount of heat needed to raise the temperature of one liter of water by one degree Celsius (or one kelvin ).