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Godshall et al. further identified the similar value of ternary compound lithium-transition metal-oxides such as the spinel LiMn 2 O 4, Li 2 MnO 3, LiMnO 2, LiFeO 2, LiFe 5 O 8, and LiFe 5 O 4 (and later lithium-copper-oxide and lithium-nickel-oxide cathode materials in 1985) [27] Godshall et al. patent U.S. patent 4,340,652 [28] for the use of ...
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li + ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life.
Lithium manganese oxide or Lithium nickel manganese cobalt oxide Yes 2008 [45] 1.6–1.8 [46] 2.3–2.4 [46] 2.8 [46] 0.22–0.40 (60–110) 0.64 (177) 3,000– 5,100 [47] 0.38 (2620) [47] 85 [47] 2–5 [47] 10–20 [47] Lithium cobalt oxide: LiCoO 2 ICR LCO Li‑cobalt [48] Graphite ‡ LiPF 6 / LiBF 4 / LiClO 4: Lithium cobalt oxide: Yes 1991 ...
NMC materials have layered structures similar to the individual metal oxide compound lithium cobalt oxide (LiCoO 2). [3] Lithium ions intercalate between the layers upon discharging, remaining between the lattice planes until the battery gets charged, at which point the lithium de-intercalates and moves to the anode. [4]
Lithium-ion battery negative electrodes are most commonly made of graphite. Graphite anodes are limited to a theoretical capacity of 372 mAh/g for their fully lithiated state. [ 4 ] At this time, significant other types of lithium-ion battery anode materials have been proposed and evaluated as alternatives to graphite, especially in cases where ...
Starting from the first cycle of lithium-ion battery operation, the electrolyte decomposes to form lithium compounds on the anode surface, producing a layer called the solid-electrolyte interface (SEI). For both silicon and graphite anodes, this SEI layer is the result of the reduction potential of the anode.