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Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...
Graham's law of effusion (also called Graham's law of diffusion) was formulated by Scottish physical chemist Thomas Graham in 1848. [1] Graham found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the molar mass of its particles. [1] This formula is stated as: where: Rate 1 is the rate of ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
The law is a specific case of the ideal gas law. A modern statement is: Avogadro's law states that "equal volumes of all gases, at the same temperature and pressure, have the same number of molecules." [1] For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are ...
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
These are analogous to Boyle's law and Charles's law for gases. Similarly, the combined ideal gas law, =, has as an analogue for ideal solutions =, where is osmotic pressure; V is the volume; n is the number of moles of solute; R is the molar gas constant 8.314 J K −1 mol −1; T is absolute temperature; and i is the Van 't Hoff factor.
Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant. Therefore, when the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved.