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Envelope (mathematics) Construction of the envelope of a family of curves. In geometry, an envelope of a planar family of curves is a curve that is tangent to each member of the family at some point, and these points of tangency together form the whole envelope. Classically, a point on the envelope can be thought of as the intersection of two ...
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
Spinodal. A phase diagram displaying spinodal curves, within the binodal coexistence curves and two critical points: an upper and lower critical solution temperature. In thermodynamics, the limit of local stability against phase separation with respect to small fluctuations is clearly defined by the condition that the second derivative of Gibbs ...
In physics, slowly varying envelope approximation[1] (SVEA, sometimes also called slowly varying asymmetric approximation or SVAA) is the assumption that the envelope of a forward-travelling wave pulse varies slowly in time and space compared to a period or wavelength. This requires the spectrum of the signal to be narrow-banded —hence it is ...
Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing. The result is an equation for the Gibbs free energy change for mixing a polymer ...
In condensed matter physics, Bloch's theorem states that solutions to the Schrödinger equation in a periodic potential can be expressed as plane waves modulated by periodic functions. The theorem is named after the Swiss physicist Felix Bloch, who discovered the theorem in 1929. [1] Mathematically, they are written [2] Bloch function.
e. The dividing line between metals and nonmetals can be found, in varying configurations, on some representations of the periodic table of the elements (see mini-example, right). Elements to the lower left of the line generally display increasing metallic behaviour; elements to the upper right display increasing nonmetallic behaviour.