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  2. Lone pair - Wikipedia

    en.wikipedia.org/wiki/Lone_pair

    Lone pairs (shown as pairs of dots) in the Lewis structure of hydroxide. In science, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bond [1] and is sometimes called an unshared pair or non-bonding pair. Lone pairs are found in the outermost electron shell of atoms.

  3. Hydroxide - Wikipedia

    en.wikipedia.org/wiki/Hydroxide

    In an aqueous solution [3] the hydroxide ion is a base in the Brønsted–Lowry sense as it can accept a proton [note 4] from a Brønsted–Lowry acid to form a water molecule. It can also act as a Lewis base by donating a pair of electrons to a Lewis acid.

  4. Lewis acids and bases - Wikipedia

    en.wikipedia.org/wiki/Lewis_acids_and_bases

    A Lewis base is often a Brønsted–Lowry base as it can donate a pair of electrons to H +; [11] the proton is a Lewis acid as it can accept a pair of electrons. The conjugate base of a Brønsted–Lowry acid is also a Lewis base as loss of H + from the acid leaves those electrons which were used for the A—H bond as a lone pair on the ...

  5. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Bent's rule can be extended to rationalize the hybridization of nonbonding orbitals as well. On the one hand, a lone pair (an occupied nonbonding orbital) can be thought of as the limiting case of an electropositive substituent, with electron density completely polarized towards the central atom.

  6. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    A water molecule has two pairs of bonded electrons and two unshared lone pairs. Tetrahedral: Tetra-signifies four, and -hedral relates to a face of a solid, so "tetrahedral" literally means "having four faces". This shape is found when there are four bonds all on one central atom, with no extra unshared electron pairs.

  7. Neighbouring group participation - Wikipedia

    en.wikipedia.org/wiki/Neighbouring_group...

    In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.

  8. Base (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Base_(chemistry)

    A Lewis base or electron-pair donor is a molecule with one or more high-energy lone pairs of electrons which can be shared with a low-energy vacant orbital in an acceptor molecule to form an adduct. In addition to H + , possible electron-pair acceptors (Lewis acids) include neutral molecules such as BF 3 and high oxidation state metal ions such ...

  9. File:Hydroxide lone pairs-2D.svg - Wikipedia

    en.wikipedia.org/wiki/File:Hydroxide_lone_pairs...

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