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Solid carbon dioxide sublimes rapidly along the solid-gas boundary (sublimation point) below the triple point (e.g., at the temperature of −78.5 °C, at atmospheric pressure), whereas its melting into liquid CO 2 can occur along the solid-liquid boundary (melting point) at pressures and temperatures above the triple point (i.e., 5.1 atm, − ...
Dry ice is the solid form of carbon dioxide (CO 2), a molecule consisting of a single carbon atom bonded to two oxygen atoms. Dry ice is colorless, odorless, and non-flammable, and can lower the pH of a solution when dissolved in water , forming carbonic acid (H 2 CO 3 ).
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately. Blue type items have an article available by ...
A molecular solid is a solid consisting of discrete molecules. The cohesive forces that bind the molecules together are van der Waals forces , dipole–dipole interactions , quadrupole interactions , π–π interactions , hydrogen bonding , halogen bonding , London dispersion forces , and in some molecular solids, coulombic interactions .
Liquid carbon dioxide is the liquid state of carbon dioxide (CO 2 ), which cannot occur under atmospheric pressure. It can only exist at a pressure above 5.1 atm (5.2 bar; 75 psi), under 31.1 °C (88.0 °F) (temperature of critical point ) and above −56.6 °C (−69.9 °F) (temperature of triple point ). [ 1 ]
In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
Supercritical carbon dioxide (s CO 2 ) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure . Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when cooled and/or pressurised sufficiently.
The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls. [19]