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In contrast, an ammonium ion consists of one nitrogen atom and four hydrogen atoms, with a charge of +1; its chemical formula is N H + 4. Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule.
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Each ion can be either monatomic (termed simple ion), such as sodium (Na +) and chloride (Cl −) in sodium chloride, or polyatomic, such as ammonium (NH + 4) and carbonate (CO 2− 3) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH −) or oxide (O 2−) are classified as bases, such as sodium hydroxide and potassium oxide.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
An atom (or ion) whose oxidation number increases in a redox reaction is said to be oxidized (and is called a reducing agent). It is accomplished by loss of one or more electrons. The atom whose oxidation number decreases gains (receives) one or more electrons and is said to be reduced. This relation can be remembered by the following mnemonics.
A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula [SiO (4-2x)− 4−x] n, where 0 ≤ x < 2. The family includes orthosilicate SiO 4− 4 (x = 0), metasilicate SiO 2− 3 (x = 1), and pyrosilicate Si 2 O 6− 7 (x = 0.5, n = 2).
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For ions, the charge on a particular atom may be denoted with a right-hand superscript. For example, Na +, or Cu 2+. The total charge on a charged molecule or a polyatomic ion may also be shown in this way, such as for hydronium, H 3 O +, or sulfate, SO 2− 4. Here + and − are used in place of +1 and −1, respectively.