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Arsenic trisulfide is the inorganic compound with the formula As 2 S 3. It is a dark yellow solid that is insoluble in water. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow.
The first breakthrough in the detection of arsenic poisoning was in 1775 when Carl Wilhelm Scheele discovered a way to change arsenic trioxide to garlic-smelling arsine gas (AsH 3), by treating it with nitric acid (HNO 3) and combining it with zinc. [3] As 2 O 3 + 6 Zn + 12 HNO 3 → 2 AsH 3 + 6 Zn(NO 3) 2 + 3 H 2 O
Arsenic sulfide may refer to: Arsenic trisulfide , As 2 S 3 , the mineral orpiment Arsenic pentasulfide , As 2 S 5 , similar structure to phosphorus pentasulfide (β-P 2 S 5 )
In organic and organometallic chemistry, trisulfide is the functional group R-S-S-S-R. Examples include: Diallyl trisulfide; Dimethyl trisulfide; Trisulfane (hydrogen trisulfide) Some inorganic compounds are also named trisulfides to reflect their stoichiometry. Examples include: Antimony trisulfide; Arsenic trisulfide; Bismuth trisulfide ...
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
James Marsh (2 September 1794 – 21 June 1846) was a British chemist who invented the Marsh test for detecting arsenic. Born in Kent, he was working as a labourer in Woolwich in the late 1810s and early 1820s, before joining the Royal Artillery. [1] He was married to Mary, and had four children, two of whom died in infancy. [2]
Arsenic trioxide can be generated via routine processing of arsenic compounds including the oxidation (combustion) of arsenic and arsenic-containing minerals in air. Illustrative is the roasting of orpiment, a typical arsenic sulfide ore. 2 As 2 S 3 + 9 O 2 → 2 As 2 O 3 + 6 SO 2
Orpiment is a common monoclinic arsenic sulfide mineral. It has a Mohs hardness of 1.5 to 2 and a specific gravity of 3.49. It melts at 300 °C (570 °F) to 325 °C (620 °F). Optically, it is biaxial (−) with refractive indices of a = 2.4, b = 2.81, g = 3.02.