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Electro-oxidation (EO or EOx), also known as anodic oxidation or electrochemical oxidation (EC), is a technique used for wastewater treatment, mainly for industrial effluents, and is a type of advanced oxidation process (AOP). [1] The most general layout comprises two electrodes, operating as anode and cathode, connected to a power source.
Microbial fuel cells (MFC) and microbial electrolysis cells (MEC) are prominent examples of METs. While MFC is used to generate electricity from organic matter typically associated with wastewater treatment, MEC use electricity to drive chemical reactions such as the production of H 2 or methane.
The mechanism of ·OH production (Part 1) highly depends on the sort of AOP technique that is used. For example, ozonation, UV/H 2 O 2, photocatalytic oxidation and Fenton's oxidation rely on different mechanisms of ·OH generation: UV/H 2 O 2: [6] [12] [13] H 2 O 2 + UV → 2·OH (homolytic bond cleavage of the O-O bond of H 2 O 2 leads to ...
Electrocoagulation (EC) is a technique used for wastewater treatment, wash water treatment, industrially processed water, and medical treatment. Electrocoagulation has become a rapidly growing area of wastewater treatment due to its ability to remove contaminants that are generally more difficult to remove by filtration or chemical treatment systems, such as emulsified oil, total petroleum ...
"Wastewater Technology Fact Sheets". Washington, D.C.: U.S. Environmental Protection Agency (EPA). 25 June 2015. Primer for Municipal Wastewater Treatment Systems (Report). EPA. 2004. EPA 832-R-04-001. Industrial Wastewater Treatment Technology Database EPA.
One common process in wastewater treatment is phase separation, such as sedimentation. Biological and chemical processes such as oxidation are another example. Polishing is also an example. The main by-product from wastewater treatment plants is a type of sludge that is usually treated in the same or another wastewater treatment plant. [2]:
The purpose of the divided cell is to permit the diffusion of ions while restricting the flow of the products and reactants. This separation simplifies workup. An example of a reaction requiring a divided cell is the reduction of nitrobenzene to phenylhydroxylamine, where the latter chemical is susceptible to oxidation at the anode.
The electrochemical mechanisms of electrocatalytic processes are a common research subject for various fields of chemistry and associated sciences. This is important to the development of water oxidation and fuel cells catalysts. For example, half the water oxidation reaction is the reduction of protons to hydrogen, the subsequent half reaction.