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Polyethylene was first synthesized by the German chemist Hans von Pechmann, who prepared it by accident in 1898 while investigating diazomethane. [12] [a] [13] [b] When his colleagues Eugen Bamberger and Friedrich Tschirner characterized the white, waxy substance that he had created, they recognized that it contained long −CH 2 − chains and termed it polymethylene.
HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
The plastic kits and covers are mostly made of synthetic polymers like polythene, and tires are manufactured from polybutadienes. [1] However, due to the environmental issues created by these synthetic polymers which are mostly non-biodegradable and often synthesized from petroleum, alternatives like bioplastics are also being considered.
The degradation of polyethylene occurs by random scission—a random breakage of the bonds that hold the atoms of the polymer together. When heated above 450 °C, polyethylene degrades to form a mixture of hydrocarbons. In the case of chain-end scission, monomers are released and this process is referred to as unzipping or depolymerization ...
To make lengths of HDPE pipe, polyethylene raw material is dried, heated to ~180 °C (356 °F), and extruded through a die. Polyethylene pipe is usually black due to the addition of 3-5% of carbon black to the clear polyethylene material, which adds UV light resistance to the finished pipe. To create striped HDPE pipe a different die is used ...
IKEA's Better Shelter uses structural panels made out of polyolefin foam, stating, "They are tough and durable.". [17] Piping systems for the conveyance of water, chemicals or gases are commonly produced in Polypropylene, and to a much greater extent Polyethylene. Piping systems in high-density Polyethylene (HDPE, PE100, PE80) are fast becoming ...
Polyethylene terephthalate is produced largely from purified terephthalic acid (PTA), as well as to a lesser extent from (mono-)ethylene glycol (MEG) and dimethyl terephthalate (DMT). [41] [5] As of 2022, ethylene glycol is made from ethene found in natural gas, while terephthalic acid comes from p-xylene made from crude oil.
A common post-extrusion process for plastic sheet stock is thermoforming, where the sheet is heated until soft (plastic), and formed via a mold into a new shape. When vacuum is used, this is often described as vacuum forming. Orientation (i.e. ability/ available density of the sheet to be drawn to the mold which can vary in depths from 1 to 36 ...