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For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
The residual dipolar coupling (RDC) occurs if the molecules in solution exhibit a partial alignment leading to an incomplete averaging of spatially anisotropic magnetic interactions i.e. dipolar couplings. RDC measurement provides information on the global folding of the protein-long distance structural information. It also provides information ...
A CML generally incorporates a system of equations (coupled or uncoupled), a finite number of variables, a global or local coupling scheme and the corresponding coupling terms. The underlying lattice can exist in infinite dimensions. Mappings of interest in CMLs generally demonstrate chaotic behavior. Such maps can be found here: List of ...
The Universal Soil Loss Equation (USLE) is a widely used mathematical model that describes soil erosion processes. [1]Erosion models play critical roles in soil and water resource conservation and nonpoint source pollution assessments, including: sediment load assessment and inventory, conservation planning and design for sediment control, and for the advancement of scientific understanding.
The dipole model of the Earth's magnetic field is a first order approximation of the rather complex true Earth's magnetic field. Due to effects of the interplanetary magnetic field (IMF), and the solar wind , the dipole model is particularly inaccurate at high L-shells (e.g., above L=3), but may be a good approximation for lower L-shells.
The full form of the J-coupling interaction between spins 'I j and I k on the same molecule is: H = 2π I j · J jk · I k. where J jk is the J-coupling tensor, a real 3 × 3 matrix. It depends on molecular orientation, but in an isotropic liquid it reduces to a number, the so-called scalar coupling. In 1D NMR, the scalar coupling leads to ...
The name cam clay asserts that the plastic volume change typical of clay soil behaviour is due to mechanical stability of an aggregate of small, rough, frictional, interlocking hard particles. [3] The Original Cam-Clay model is based on the assumption that the soil is isotropic, elasto-plastic, deforms as a continuum, and it is not affected by ...
The Global Ocean Data Analysis Project (GLODAP) is a synthesis project bringing together oceanographic data, featuring two major releases as of 2018. The central goal of GLODAP is to generate a global climatology of the World Ocean 's carbon cycle for use in studies of both its natural and anthropogenically forced states.