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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
It belongs to the spinel group of minerals, as does magnetite, Fe 3 O 4. Ulvöspinel forms as solid solutions with magnetite at high temperatures and reducing conditions, and grains crystallized from some basalt-gabbro magmas are rich in the ulvöspinel component.
Spinel gemstones (1 C, 6 P) Pages in category "Spinel group" The following 19 pages are in this category, out of 19 total. This list may not reflect recent changes. ...
The mineral ceylonite has the chemical composition of (Mg, Fe 2+) Al 2 O 4, putting it into a group of minerals known as the spinel group, or the oxide spinels. The oxide spinels have a formula of the model [A][B] 2 O 4; where [A] is commonly Fe 2+, Mg 2+, or Mn 2+, and [B] is Fe 3+, Al 3+, or Cr 3+. It is an iron-rich variety of the spinel ...
The thiospinel group is a group of sulfide minerals with a general formula AB 2 X 4 where A is nominally a +2 metal, B is a +3 metal and X is -2 sulfide or similar anion (selenide or telluride).
This is the case for spinel law twinning on <111>: The spinel structure has a 3-fold rotational symmetry on <111> and spinel is commonly twinned by 2-fold rotation on <111>. [1] The boundary between crystal segments is called a composition surface or, if it is planar, a composition plane. The composition plane is often, though not always ...
Most pieces of the gem, prior to Taaffe, had been misidentified as spinel. For many years afterwards, it was known only in a few samples, and it is still one of the rarest gemstone minerals in the world. [6] Since 2002, the International Mineralogical Association-approved name for taaffeite as a mineral is magnesiotaaffeite-2N'2S.