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At pH below 2, the majority of the chlorine in the solution is in the form of dissolved elemental Cl 2. At pH greater than 7.4, the majority is in the form of hypochlorite ClO −. [10] The equilibrium can be shifted by adding acids (such as hydrochloric acid) or bases (such as sodium hydroxide) to the solution:
For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
In a paper published in 1894, it was formally proposed to add chlorine to water to render it "germ-free". Two other authorities endorsed this proposal and published it in many other papers in 1895. [4] Early attempts at implementing water chlorination at a water treatment plant were made in 1893 in Hamburg, Germany.
At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl.
They range from those of water at very low concentrations approaching 0% HCl to values for fuming hydrochloric acid at over 40% HCl. [ 31 ] [ 32 ] [ 33 ] Hydrochloric acid as the binary (two-component) mixture of HCl and H 2 O has a constant-boiling azeotrope at 20.2% HCl and 108.6 °C (381.8 K; 227.5 °F).
2 HClO(aq) + 2 H + + 2 e − ⇌ Cl 2 (g) + 2 H 2 O, E = +1.63 V. HClO reacts with HCl to form chlorine: HClO + HCl → H 2 O + Cl 2. HClO reacts with ammonia to form monochloramine: NH 3 + HClO → NH 2 Cl + H 2 O. HClO can also react with organic amines, forming N-chloroamines. Hypochlorous acid exists in equilibrium with its anhydride ...
Ingestion of ammonium chloride, hydrochloric acid, or other acidifying salts; The treatment and recovery phases of diabetic ketoacidosis; Volume resuscitation with 0.9% normal saline provides a chloride load, so that infusing more than 3–4L can cause acidosis; Hyperalimentation (i.e., total parenteral nutrition)
The Winkler test is used to determine the concentration of dissolved oxygen in water samples. Dissolved oxygen (D.O.) is widely used in water quality studies and routine operation of water reclamation facilities to analyze its level of oxygen saturation. In the test, an excess of manganese(II) salt, iodide (I −) and hydroxide (OH −) ions ...