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Dispersive prisms are used to break up light into its constituent spectral colors because the refractive index depends on wavelength; the white light entering the prism is a mixture of different wavelengths, each of which gets bent slightly differently. Blue light is slowed more than red light and will therefore be bent more than red light.
Photograph of a triangular prism, dispersing light Lamps as seen through a prism. In optics, a dispersive prism is an optical prism that is used to disperse light, that is, to separate light into its spectral components (the colors of the rainbow). Different wavelengths (colors) of light will be deflected by the prism at different angles. [1]
The prism refracts light into its different colors (wavelengths). The dispersion occurs because the angle of refraction is dependent on the refractive index of the prism's material, which in turn is slightly dependent on the wavelength of light that is traveling through it.
The prism causes the light to disperse and fan out into a rainbow-like spectrum. For each packet of white light entering the prism, a color-dispersed packet of light exits the prism. Because light travels slower in glass than in air, the packets necessarily bunch up inside the prism and only resume their normal speed (and spacing) after exiting.
From Snell's law it can be seen that the angle of refraction of light in a prism depends on the refractive index of the prism material. Since that refractive index varies with wavelength, it follows that the angle that the light is refracted by will also vary with wavelength, causing an angular separation of the colors known as angular dispersion.
Schematic setup of an automatic refractometer: An LED light source is imaged under a wide range of angles onto a prism surface which is in contact with a sample. Depending on the difference in the refractive index between prism material and sample the light is partly transmitted or totally reflected.
The light then passed through a prism (in hand-held spectroscopes, usually an Amici prism) that refracted the beam into a spectrum because different wavelengths were refracted different amounts due to dispersion. This image was then viewed through a tube with a scale that was transposed upon the spectral image, enabling its direct measurement.
Refraction at interface. Many materials have a well-characterized refractive index, but these indices often depend strongly upon the frequency of light, causing optical dispersion. Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers.