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X-ray absorption spectroscopy (XAS) is a widely used technique for determining the local geometric and/or electronic structure of matter. [1] The experiment is usually performed at synchrotron radiation facilities, which provide intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. [2]
Extended X-ray absorption fine structure (EXAFS), along with X-ray absorption near edge structure , is a subset of X-ray absorption spectroscopy . Like other absorption spectroscopies , XAS techniques follow Beer's law .
The XANES energy region [3] extends between the edge region and the EXAFS region over a 50-100 eV energy range around the core level x-ray absorption threshold. Before 1980 the XANES region was wrongly assigned to different final states: a) unoccupied total density of states, or b) unoccupied molecular orbitals (kossel structure) or c) unoccupied atomic orbitals or d) low energy EXAFS ...
X-ray absorption near edge structure (XANES), also known as near edge X-ray absorption fine structure (NEXAFS), is a type of absorption spectroscopy that indicates the features in the X-ray absorption spectra of condensed matter due to the photoabsorption cross section for electronic transitions from an atomic core level to final states in the energy region of 50–100 eV above the selected ...
In electron microscopy an electron beam excites X-rays; there are two main techniques for analysis of spectra of characteristic X-ray radiation: energy-dispersive X-ray spectroscopy (EDS) and wavelength dispersive X-ray spectroscopy (WDS). In X-ray transmission (XRT), the equivalent atomic composition (Z eff) is captured based on photoelectric ...
Surface-extended X-ray absorption fine structure (SEXAFS) is the surface-sensitive equivalent of the EXAFS technique. This technique involves the illumination of the sample by high-intensity X-ray beams from a synchrotron and monitoring their photoabsorption by detecting in the intensity of Auger electrons as a function of the incident photon energy.
PIRX (previously XAS) is a bending-magnet-based beamline dedicated to microscopy and spectroscopy in the soft X-ray energy range.The beamline is designed to study chemical and electronic, structural and magnetic properties by means of X-ray absorption spectroscopy (XAS), X-ray natural linear dichroism (XNLD) and X-ray magnetic circular dichroism (XMCD), X-ray magnetic linear dichroism (XMLD ...
XAES – X-ray induced Auger electron spectroscopy; XANES – XANES, synonymous with NEXAFS (near edge X-ray absorption fine structure) XAS – X-ray absorption spectroscopy; X-CTR – X-ray crystal truncation rod scattering; X-ray crystallography; XDS – X-ray diffuse scattering; XES – X-ray emission spectroscopy