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In stereochemistry, prochiral molecules are those that can be converted from achiral to chiral in a single step. [1] [2] An achiral species which can be converted to a chiral in two steps is called proprochiral. [2] If two identical substituents are attached to an sp 3-hybridized atom, the descriptors pro-R and pro-S are used to distinguish ...
Hartwig and co-workers have succeeded in developing highly selective iridium catalysts with (R,R,R)-phosphoramidite L [11] The allylic aminations of a wide variety of achiral allylic esters proceeded with total conversion and superb regioselectivity in many cases. The reaction shown clearly illustrates the power of this methodology, wherein ...
Under certain conditions, some battery chemistries are at risk of thermal runaway, leading to cell rupture or combustion.As thermal runaway is determined not only by cell chemistry but also cell size, cell design and charge, only the worst-case values are reflected here.
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A variety of different kinds of IEC 60320 plugs and sockets. IEC 60320 Appliance couplers for household and similar general purposes [1] is a set of standards from the International Electrotechnical Commission (IEC) specifying non-locking connectors for connecting power supply cords to electrical appliances of voltage not exceeding 250 V (a.c.) and rated current not exceeding 16 A. [1 ...
powerCON is an electrical connector manufactured by Neutrik for connecting mains power to equipment in a small space. It looks and works similarly to the Speakon connector, with the line connector inserted in the chassis connector and twisted to make contact and lock. Both line and chassis connectors are fully insulated even when disconnected.
The connector provides power to the keyboard on the outer two contacts and receives data signals on the inner pair. The cable between the computer and the keyboard is a coiled cord with an appearance very similar to a telephone handset cable. [11] The connector on the Amiga 1000 uses crossover wiring, similar to a telephone handset.
The Corey–Itsuno reduction, also known as the Corey–Bakshi–Shibata (CBS) reduction, is a chemical reaction in which a prochiral ketone is enantioselectively reduced to produce the corresponding chiral, non-racemic alcohol.