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The process, which is catalyzed by platinum supported by aluminium oxide, is exemplified in the conversion methylcyclohexane (a naphthene) into toluene (an aromatic). [2] Dehydrocyclization converts paraffins (acyclic hydrocarbons) into aromatics. [3] A related aromatization process includes dehydroisomerization of methylcyclopentane to benzene:
Cyclopentadiene is a highly reactive diene in the Diels–Alder reaction because minimal distortion of the diene is required to achieve the envelope geometry of the transition state compared to other dienes. [11] Famously, cyclopentadiene dimerizes. The conversion occurs in hours at room temperature, but the monomer can be stored for days at ...
The Sandmeyer reaction can also be used to convert aryl amines to phenols proceeding through the formation of an aryl diazonium salt. In the presence of copper catalyst, such as copper(I) oxide , and an excess of copper(II) nitrate , this reaction takes place readily at room temperature neutral water. [ 28 ]
And while food poisoning can happen anywhere, fast-food chains have seen some of the worst outbreaks due to their massive scale. Data from iwaspoisoned.com, a food safety reporting platform, shows ...
Benzene in soft drinks has to be seen in the context of other environmental exposure. Taking the worst example found to date of a soft drink containing 87.9 ppb benzene, [5] someone drinking a 350 ml (12 oz) can would ingest 31 μg (micrograms) of benzene, almost equivalent to the benzene inhaled by a motorist refilling a fuel tank for three ...
Methylene-interrupted polyenes are 1,4-pentadiene groups found in polyunsaturated fatty acids linoleic acid, α-linolenic acid, and arachidonic acid.These pentadiene derivatives are susceptible to lipid peroxidation, far moreso than monounsaturated or saturated fatty acids.
Foodborne illness (also known as foodborne disease and food poisoning) [1] is any illness resulting from the contamination of food by pathogenic bacteria, viruses, or parasites, [2] as well as prions (the agents of mad cow disease), and toxins such as aflatoxins in peanuts, poisonous mushrooms, and various species of beans that have not been boiled for at least 10 minutes.
An alkyne trimerisation is a [2+2+2] cycloaddition reaction in which three alkyne units (C≡C) react to form a benzene ring. The reaction requires a metal catalyst.The process is of historic interest as well as being applicable to organic synthesis. [1]