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Lithium 12-hydroxystearate exhibits high oxidation stability and a dropping point up to around 200 °C. Most greases used today in motor vehicles, aircraft, and heavy machinery contain lithium stearates, mainly lithium 12-hydroxystearate. [1] Greases can be made with the addition of several different metallic soaps.
Lithium-based grease has a dropping point at 190 to 220 °C (374 to 428 °F). However the maximum usable temperature for lithium-based grease is 120 °C. The amount of grease in a sample can be determined in a laboratory by extraction with a solvent followed by e.g. gravimetric determination. [6]
Lithium grease adheres particularly well to metal, is non-corrosive, may be used under heavy loads, and exhibits good temperature tolerance. It has a dropping point of 190 to 220 °C (370 to 430 °F) and resists moisture, so it is commonly used as lubricant in household products, such as electric garage doors, as well as in automotive ...
The third most common use of lithium is in greases. Lithium hydroxide is a strong base, and when heated with a fat, it produces a soap, such as lithium stearate from stearic acid. Lithium soap has the ability to thicken oils, and it is used to manufacture all-purpose, high-temperature lubricating greases. [21] [162] [163]
Lithium 12-hydroxystearate and other lithium-based fatty acids are important constituents of lubricating greases. In lithium-based greases, lithium carboxylates are thickeners. "Complex soaps" are also common, these being combinations of more than one acid salt, such as azelaic or acetic acid. [7]
Lithium soap or greases, such as lithium stearate, are insoluble in water and find use in lubricating grease. Calcium and magnesium soaps are most commonly encountered as soap scum but the pure materials have a variety of uses.