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1,4-Benzoquinone, commonly known as para-quinone, is a chemical compound with the formula C 6 H 4 O 2. In a pure state, it forms bright-yellow crystals with a characteristic irritating odor, resembling that of chlorine, bleach, and hot plastic or formaldehyde. This six-membered ring compound is the oxidized derivative of 1,4-hydroquinone. [4]
While for 1,4-pentadiene the sp 2-hybridization leads to a bond angle of 120° between the single and double bond, in 1,4-pentadiyne it is a 180° angle due to the sp-hybrid orbital. Both triple bonds in 1,4-position destabilize each other according to another study by 3.9 kcal · mol −1 , a repulsion between the p orbital lobes close to the ...
Tetrahydroxy-1,4-benzoquinone, also called tetrahydroxy-p-benzoquinone, tetrahydroxybenzoquinone, or tetrahydroxyquinone (THBQ, THQ), is an organic compound with formula C 6 O 2 (OH) 4. Its molecular structure consists of a cyclohexadiene ring with four hydroxyl groups and two ketone groups in opposite ( para ) positions.
These groups can be cis or trans. Other isomers of cyclohexanedicarboxylic acid are known, but the 1,4- isomers are of greatest interest, perhaps because they are obtainable from a commodity chemical. Specifically, hydrogenation of terephthalic acid affords the title compound: [1] C 6 H 4 (CO 2 H) 2 + 3 H 2 → C 6 H 10 (CO 2 H) 2.
It is a yellow solid [1] with planar molecules [2] that exhibits ferroelectric properties. [3] The compound is a weak acid: one or both hydroxyls can lose a proton to yield the anions C 6 H 3 O − 4 (pK a1 = 2.95) and C 6 H 2 O 2− 4 (pK a2 = 4.87), respectively. The latter forms a variety of metal complexes, functioning as a binucleating ...
The reaction conducted in two steps beginning with the conversion of DMT to the diester dimethyl 1,4-cyclohexanedicarboxylate (DMCD): C 6 H 4 (CO 2 CH 3) 2 + 3 H 2 → C 6 H 10 (CO 2 CH 3) 2. In the second step DMCD is further hydrogenated to CHDM: C 6 H 10 (CO 2 CH 3) 2 + 4 H 2 → C 6 H 10 (CH 2 OH) 2 + 2 CH 3 OH. A copper chromite catalyst ...
1,4-Dimethylnaphthalene (1,4DMN) is a plant growth regulator that occurs naturally in potato tubers, preventing them from sprouting. [1] Synthetic forms such as 1-4SIGHT are applied to potatoes during storage. [2] Although discovered in the 1970s, it was not used commercially in the USA until 1996 [3] and in Europe until the 2010s. [4]
1,4-Butynediol is a precursor to 1,4-butanediol and 2-butene-1,4-diol by hydrogenation. It is also used in the manufacture of certain herbicides, textile additives, corrosion inhibitors, plasticizers, synthetic resins, and polyurethanes. It is the major raw material used in the synthesis of vitamin B 6. [5]