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The wave function of an initially very localized free particle. In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters ψ and Ψ (lower-case and capital psi, respectively). Wave functions are complex ...
While the time-evolution process represented by the Schrödinger equation is continuous and deterministic, in that knowing the wave function at one instant is in principle sufficient to calculate it for all future times, wave functions can also change discontinuously and stochastically during a measurement. The wave function changes, according ...
Variational method (quantum mechanics) In quantum mechanics, the variational method is one way of finding approximations to the lowest energy eigenstate or ground state, and some excited states. This allows calculating approximate wavefunctions such as molecular orbitals. [1] The basis for this method is the variational principle. [2][3]
Wave function normalization is scaling a wave function so that its norm is 1. Since virtually every calculation in quantum mechanics involves vectors and linear operators, it can involve, and often does involve, bra–ket notation. A few examples follow:
Probability amplitude. A wave function for a single electron on 5d atomic orbital of a hydrogen atom. The solid body shows the places where the electron's probability density is above a certain value (here 0.02 nm −3): this is calculated from the probability amplitude. The hue on the colored surface shows the complex phase of the wave function.
The Born rule is a postulate of quantum mechanics that gives the probability that a measurement of a quantum system will yield a given result. In one commonly used application, it states that the probability density for finding a particle at a given position is proportional to the square of the amplitude of the system's wavefunction at that position.
e. In physics, specifically relativistic quantum mechanics (RQM) and its applications to particle physics, relativistic wave equations predict the behavior of particles at high energies and velocities comparable to the speed of light. In the context of quantum field theory (QFT), the equations determine the dynamics of quantum fields.
Planck–Einstein equation and de Broglie wavelength relations. P = (E/c, p) is the four-momentum, K = (ω / c, k) is the four-wavevector, E = energy of particle. ω = 2π f is the angular frequency and frequency of the particle. ħ = h /2π are the Planck constants. c = speed of light.