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In some reactions between highly reactive metals (usually from Group 1 or Group 2) and highly electronegative halogen gases, or water, the atoms can be ionized by electron transfer, [16] a process thermodynamically understood using the Born–Haber cycle. [17] Salts are formed by salt-forming reactions. A base and an acid, e.g., NH 3 + HCl → ...
The term typically applies in electrochemistry, when electrical energy in the form of an applied voltage is used to modulate the thermodynamic favorability of a chemical reaction. In a battery, an electrochemical potential arising from the movement of ions balances the reaction energy of the electrodes.
When an oxidizer (Ox) accepts a number z of electrons ( e −) to be converted in its reduced form (Red), the half-reaction is expressed as: Ox + z e − → Red. The reaction quotient (Q r) is the ratio of the chemical activity (a i) of the reduced form (the reductant, a Red) to the activity of the oxidized form (the oxidant, a ox).
Example of a reduction–oxidation reaction between sodium and chlorine, with the OIL RIG mnemonic [1] Electron transfer (ET) occurs when an electron relocates from an atom, ion, or molecule, to another such chemical entity. ET describes the mechanism by which electrons are transferred in redox reactions. [2] Electrochemical processes are ET
The salt can be recovered by evaporation of the solvent. An electrolyte refers to a substance that contains free ions and can be used as an electrically conductive medium. Most of the solute does not dissociate in a weak electrolyte, whereas in a strong electrolyte a higher ratio of solute dissociates to form free ions.
Two common modes of Lewis acid catalysis in reactions with polar mechanisms. In reactions with polar mechanisms, Lewis acid catalysis often involves binding of the catalyst to Lewis basic heteroatoms and withdrawing electron density, which in turn facilitates heterolytic bond cleavage (in the case of Friedel-Crafts reaction) or directly activates the substrate toward nucleophilic attack (in ...
For example, a change of reaction medium from hexane to water increases the rate of tert-Butyl chloride (t-BuCl) heterolysis by 14 orders of magnitude. [5] This is caused by very strong solvation of the transition state. The main factors that affect heterolysis rates are mainly the solvent's polarity and electrophilic as well as its ionizing power.
The reaction at the anode results in chlorine gas from chlorine ions: 2 Cl − → Cl 2 + 2 e −. The reaction at the cathode results in hydrogen gas and hydroxide ions: 2 H 2 O + 2 e − → H 2 + 2 OH −. Without a partition between the electrodes, the OH − ions produced at the cathode are free to diffuse throughout the electrolyte to the ...