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The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5] This makes it a very dangerous compound to the organism. [6] [7] Unlike superoxide, which can be detoxified by superoxide dismutase, the hydroxyl radical cannot be eliminated by an enzymatic reaction.
Hydroxyl radical (HO·) is generated by Fenton reaction of hydrogen peroxide with ferrous compounds and related reducing agents: Fe(II) + H 2 O 2 → Fe(III)OH + HO· In its fleeting existence, the hydroxyl radical reacts rapidly irreversibly with all organic compounds. superoxide (O − 2) is produced by reduction of O 2. [4]
Oxidative stress mechanisms in tissue injury. Free radical toxicity induced by xenobiotics and the subsequent detoxification by cellular enzymes (termination).. Oxidative stress reflects an imbalance between the systemic manifestation of reactive oxygen species and a biological system's ability to readily detoxify the reactive intermediates or to repair the resulting damage. [1]
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry , alcohols and carboxylic acids contain one or more hydroxy groups.
VHP is produced from a solution of liquid H 2 O 2 and water, by generators specifically designed for the purpose. These generators initially dehumidify the ambient air, then produce VHP by passing aqueous hydrogen peroxide over a vaporizer, and circulate the vapor at a programmed concentration in the air, typically from 140 ppm to 1400 ppm, depending on the infectious agent to be cleared. [6]
Catalyst poisoning is the partial or total deactivation of a catalyst by a chemical compound. Poisoning refers specifically to chemical deactivation, rather than other mechanisms of catalyst degradation such as thermal decomposition or physical damage.
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In the atmosphere, PCBs may be degraded by hydroxyl radicals, or directly by photolysis of carbon–chlorine bonds (even if this is a less important process). [ 38 ] Atmospheric concentrations of PCBs tend to be lowest in rural areas, where they are typically in the picogram per cubic meter range, higher in suburban and urban areas, and highest ...