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An adiabatic process (adiabatic from Ancient Greek ἀδιάβατος (adiábatos) 'impassable') is a type of thermodynamic process that occurs without transferring heat between the thermodynamic system and its environment. Unlike an isothermal process, an adiabatic process transfers energy to the surroundings only as work and/or mass flow.
The adiabatic (no heat exchanged) expansion of a gas may be carried out in a number of ways. The change in temperature experienced by the gas during expansion depends not only on the initial and final pressure, but also on the manner in which the expansion is carried out.
The exponent, , with which the expansion of the gas can be calculated by the application of heat is called the isentropic – or adiabatic coefficient. Its value is determined by the Rüchardt experiment. An adiabatic and reversible running state change is isentropic (entropy S remains the same as temperature T changes). The technique is ...
The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the ...
We assume the expansion occurs without exchange of heat (adiabatic expansion). Doing this work, air inside the cylinder will cool to below the target temperature. To return to the target temperature (still with a free piston), the air must be heated, but is no longer under constant volume, since the piston is free to move as the gas is reheated.
Free expansion; Reversibility; ... Equations Isentropic process (adiabatic and reversible) ... Work done by an expanding gas Process = ...
Under other conditions, free-energy change is not equal to work; for instance, for a reversible adiabatic expansion of an ideal gas, =. Importantly, for a heat engine, including the Carnot cycle , the free-energy change after a full cycle is zero, Δ cyc A = 0 {\displaystyle \Delta _{\text{cyc}}A=0} , while the engine produces nonzero work.
Adiabatic process: occurs without loss or gain of energy by heat; Isenthalpic process: occurs at a constant enthalpy; Isentropic process: a reversible adiabatic process, occurs at a constant entropy; Isobaric process: occurs at constant pressure; Isochoric process: occurs at constant volume (also called isometric/isovolumetric)