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EC-AFM allows to perform in-situ AFM measurements in an electrochemical cell, in order to investigate the actual changes in the electrode surface morphology during electrochemical reactions. The solid-liquid interface is thus investigated. [ 1 ]
Electrochemical quartz crystal microbalance (EQCM) is the combination of electrochemistry and quartz crystal microbalance, which was generated in the eighties. [1] [2] [3] Typically, an EQCM device contains an electrochemical cells part and a QCM part. [4] Two electrodes on both sides of the quartz crystal serve two purposes. [4]
Electrochemical reactions occur in electrolytic solutions—for example electroplating, etching, batteries, and so on.On the electrode surface, many atoms, molecules, and ions adsorb and affect the reactions.
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. One electrode is called the reference electrode and has a constant potential, while the other one is an indicator electrode whose potential changes with the sample's composition.
Spectroscopic and electrochemical techniques that form the spectroelectrochemistry. Spectroelectrochemistry (SEC) is a set of multi-response analytical techniques in which complementary chemical information (electrochemical and spectroscopic) is obtained in a single experiment.
In situ electron microscopy is an investigatory technique where an electron microscope is used to watch a sample's response to a stimulus in real time. Due to the nature of the high-energy beam of electrons used to image a sample in an electron microscope, microscopists have long observed that specimens are routinely changed or damaged by the electron beam.
In electrochemistry, the Randles–ŠevĨík equation describes the effect of scan rate on the peak current (i p) for a cyclic voltammetry experiment. For simple redox events where the reaction is electrochemically reversible, and the products and reactants are both soluble, such as the ferrocene/ferrocenium couple, i p depends not only on the concentration and diffusional properties of the ...
In recent years Raman-SEC has become an important tool in the study of electrochemical processes and in the characterization of many molecules, providing specific in situ information about them. Some applications are: [ 1 ] [ 10 ] [ 14 ] [ 20 ]