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Traditionally Grignard reagents are prepared by treating an organic halide (normally organobromine) with magnesium metal. Ethers are required to stabilize the organomagnesium compound.
In secondary (2°) haloalkanes, the carbon that carries the halogen atom has two C–C bonds. In tertiary (3°) haloalkanes, the carbon that carries the halogen atom has three C–C bonds. [citation needed] Haloalkanes can also be classified according to the type of halogen on group 17 responding to a specific halogenoalkane.
haloalkanes—compounds with carbon atoms linked by single bonds; haloalkenes—compounds with one or more double bonds between carbon atoms; haloaromatics—compounds with carbons linked in one or more aromatic rings with a delocalised donut shaped pi cloud.
Bromoethane, also known as ethyl bromide, is a chemical compound of the haloalkanes group. It is abbreviated by chemists as EtBr (which is also used as an abbreviation for ethidium bromide). This volatile compound has an ether-like odor.
In general, the reaction of a haloalkane with potassium hydroxide can compete with an S N 2 nucleophilic substitution reaction by OH − a strong, unhindered nucleophile. Alcohols are however generally minor products. Dehydrohalogenations often employ strong bases such as potassium tert-butoxide (K + [CH 3] 3 CO −).
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