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Diisopropyl ether forms explosive peroxides upon standing in air. This reaction proceeds more easily than for ethyl ether due to the increased lability of the C-H bond adjacent to oxygen. Many explosions have been known to occur during handling or processing of old diisopropyl ether. [7]
In chemistry, alkyl is a group, a substituent, that is attached to other molecular fragments. For example, alkyl lithium reagents have the empirical formula Li(alkyl), where alkyl = methyl, ethyl, etc. A dialkyl ether is an ether with two alkyl groups, e.g., diethyl ether O(CH 2 CH 3) 2.
DIPEA is a sterically hindered organic base that is commonly employed as a proton scavenger. Thus, like 2,2,6,6-tetramethylpiperidine and triethylamine, DIPEA is a good base but a poor nucleophile, DIPEA has low solubility in water, which makes it very easily recovered in commercial processes, a combination of properties that makes it a useful organic reagent.
For example, ethyl methyl ether (CH 3 OC 2 H 5), diphenylether (C 6 H 5 OC 6 H 5). As for other organic compounds, very common ethers acquired names before rules for nomenclature were formalized. Diethyl ether is simply called ether, but was once called sweet oil of vitriol. Methyl phenyl ether is anisole, because it was originally found in ...
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
An ester of carboxylic acid.R stands for any group (organic or inorganic) and R′ stands for organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (−R).
Ether cleavage refers to chemical substitution reactions that lead to the cleavage of ethers. Due to the high chemical stability of ethers, the cleavage of the C-O bond is uncommon in the absence of specialized reagents or under extreme conditions. [1] [2] In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction.
As is typical of ethers, dipropyl ether may slowly form explosive organic peroxides over long periods in storage. [2] Antioxidants such as butylated hydroxytoluene are often added to ethers to prevent this process. [4] Due to the shock and light sensitive nature of organic peroxides, dipropyl ether should never be boiled or evaporated to dryness.