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Coupling reactions are a class of metal-catalyzed reactions involving an organometallic compound RM and an organic halide R′X that together react to form a compound of the type R-R′ with formation of a new carbon–carbon bond. Examples include the Heck reaction, Ullmann reaction, and Wurtz–Fittig reaction. Many variations exist. [3]
A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as: + +
Another example of a double displacement reaction is the reaction of lead(II) nitrate with potassium iodide to form lead(II) iodide and potassium nitrate: + + Forward and backward reactions According to Le Chatelier's Principle , reactions may proceed in the forward or reverse direction until they end or reach equilibrium .
A gas evolution reaction is a chemical reaction in which one of the end products is a gas such as oxygen or carbon dioxide. [ 1 ] [ 2 ] Gas evolution reactions may be carried out in a fume chamber when the gases produced are poisonous when inhaled or explosive.
In the gas phase, the comproportionation reaction is much faster because of the much higher mobility of the reacting species as illustrated, e.g., in the Claus reaction where H 2 S and SO 2 react together to form elemental sulfur. Various classical comproportionation reactions are detailed in the series of examples here below.
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
The example of dinitrogen tetroxide (N 2 O 4) dissociating to nitrogen dioxide (NO 2) will be taken. N 2 O 4 ↽ − − ⇀ 2 NO 2 {\displaystyle {\ce {N2O4 <=> 2NO2}}} If the initial concentration of dinitrogen tetroxide is 1 mole per litre , this will decrease by α at equilibrium giving, by stoichiometry, α moles of NO 2 .
[1] [2] The third law is also more generally stated as: "To every action there is always opposed an equal reaction: or the mutual actions of two bodies upon each other are always equal, and directed to contrary parts." [3] The attribution of which of the two forces is the action and which is the reaction is arbitrary. Either of the two can be ...