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Tetraoxygen was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of liquid oxygen to obey Curie's law. [1] Though not entirely inaccurate, computer simulations indicate that although there are no stable O 4 molecules in liquid oxygen, O 2 molecules do tend to associate in pairs with antiparallel spins, forming transient O 4 units. [2]
Tetraoxygen had been suspected to exist since the early 1900s, when it was known as oxozone. It was identified in 2001 by a team led by Fulvio Cacace at the University of Rome. [13] The molecule O 4 was thought to be in one of the phases of solid oxygen later identified as O 8.
The tetraoxygen molecule (O 4) was predicted in 1924 by Gilbert N. Lewis, who proposed it to explain why liquid oxygen defied Curie's law. [6] Modern computer simulations indicate that, although there are no stable O 4 molecules in liquid oxygen, O 2 molecules do tend to associate in pairs with antiparallel spins, forming transient O 4 units. [7]
The metastable molecule tetraoxygen (O 4) was discovered in 2001, [45] [46] and was assumed to exist in one of the six phases of solid oxygen. It was proven in 2006 that this phase, created by pressurizing O 2 to 20 GPa, is in fact a rhombohedral O 8 cluster. [47] This cluster has the potential to be a much more powerful oxidizer than either O ...
Even the chemical formula of O 4, tetraoxygen, is predictable as a group 16 element. One exception is copper, for which the highest oxidation state oxide is copper(II) oxide and not copper(I) oxide. Another exception is fluoride, which does not exist as one might expect—as F 2 O 7 —but as OF 2. [12]
Its bulk properties partly result from the interaction of its component atoms, oxygen and hydrogen, with atoms of nearby water molecules. Hydrogen atoms are covalently bonded to oxygen in a water molecule but also have an additional attraction (about 23.3 kJ·mol −1 per hydrogen atom) to an adjacent oxygen atom in a separate molecule. [2]
Tetraoxygen difluoride is dark red-brown as a solid and has a melting point around −191 °C. [1] It is a strong fluorinating and oxidizing agent, even stronger than dioxygen difluoride, so that it can, for example, oxidize Ag(II) to Ag(III) or Au(III) to Au(V). This process creates the corresponding anions AgF-4 and AuF-6. With non-noble ...
Gilbert Newton Lewis ForMemRS [1] (October 23 [2] [3] [4] or October 25, 1875 – March 23, 1946) [1] [5] [6] was an American physical chemist and a dean of the college of chemistry at University of California, Berkeley.