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In any case, the context and/or unit of the gas constant should make it clear as to whether the universal or specific gas constant is being referred to. [ 10 ] In case of air, using the perfect gas law and the standard sea-level conditions (SSL) (air density ρ 0 = 1.225 kg/m 3 , temperature T 0 = 288.15 K and pressure p 0 = 101 325 Pa ), we ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature. For example, in SI units R = 8.3145 J⋅K −1 ⋅mol −1 when pressure is expressed in pascals, volume in cubic meters, and absolute temperature in kelvin. The ideal gas law is an extension of experimentally discovered ...
where P is the pressure, V is the volume, N is the number of gas molecules, k B is the Boltzmann constant (1.381×10 −23 J·K −1 in SI units) and T is the absolute temperature. These equations are exact only for an ideal gas, which neglects various intermolecular effects (see real gas). However, the ideal gas law is a good approximation for ...
The standard unit is the meter cubed per kilogram (m 3 /kg or m 3 ·kg −1). Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance. In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely ...
It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure. It is a useful thermodynamic property for modifying the ideal gas law to account for the real gas behaviour. [ 1 ]
His calculation gave rise to the concept of the Loschmidt constant, a ratio between macroscopic and atomic quantities. In 1910, Millikan's oil drop experiment determined the charge of the electron ; using it with the Faraday constant (derived by Michael Faraday in 1834), one is able to determine the number of particles in a mole of substance.
Having the same units on both sides of an equation does not ensure that the equation is correct, but having different units on the two sides (when expressed in terms of base units) of an equation implies that the equation is wrong. For example, check the universal gas law equation of PV = nRT, when: the pressure P is in pascals (Pa)